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Colorless, kipyatyaschiysya gas with a sharp flavor strangulation; base point, -100.4 ? C.1, 2
Chemical Properties
{} Soluble Soluble in water with some decomposition forming fluoroboric and boric acid;
Several soluble soluble {} in concentrated sulfuric} {intensive acid and nitric acid, soluble {} soluble in benzene,
dichlorobenzene, chloroform, carbon tetrachloride and carbon disulfide 1.2
Hazardous Reactions
Alkali metal or alkaline earth metals (not magnesium). Interaction without cooling
heat 2 reasons
Physiological Properties and Health Hazards
The gas irritates the skin, eyes and respiratory system, at high concentrations it can burn
skin. Prevent inhalation of gas. Prevent contact with skin and eyes.2 TLV-STEL-C 1
ppm (2.8 mg/m3) .3
Waste Disposal
Cylinder print and return to the supplier. In the hood, smoke, excessive gas or leaking cylinder can
slowly add to the jar containing water. Accelerate the fluoride in the solution by adding
solution of calcium chloride (10%). Let stand overnight suddenly {}. Filter off faster and sends a
landfill. Wash the filtrate into the drain 4
Boron Trifluoride Complexes
Liquid Liquid} {complex formed between boron trifluoride and acetic acid, diethyl ether,
methanol and propanol show all the dangers and toxic effects are associated with them
elements {voters}. All are readily hydrolyzed by water, the correlation
roziyny and, to some extent,
Flammable 2
AZ of chemical names {Name} 101
Instruction Break
Wear nitrile rubber gloves, laboratory coats, eye protection, and, if necessary, separate
breathing apparatus. Close Embrace} {shed 1:1:1 mixture by weight of sodium
carbonate or calcium carbonate, clay cat litter (bentonite), and sand. When the boron
trifluoride complex was absorbed, scoop mixture into sulphuric acid a plastic bucket, and in
smoke hood, slowly add the mixture to a bucket of cold water. Let stand for 24
hours. Check the pH solutions and neutralize if necessary with sodium carbonate.
Filter the solution leakage. Consider the solid residue as normal failure 5
Waste Disposal
Party Pack. Place in a separate labeled container for recycling or disposal.
Small quantities. Wear nitrile rubber gloves, laboratory coats and eye protection. In
smoke hood, pour the boron trifluoride complex in a large evaporating dish. Cover
boron trifluoride complex with additional solid sodium carbonate or calcium carbonate.
When the reaction is awake, very slowly add the mixture to a bucket of cold water.
Let stand for 24 hours. Check the pH solutions and neutralize if necessary. Wash
decision drain.2-5
Reaction to breaking and Waste Orders
LINKS {Recommendations}
1. Merck 13,513,391.
2. Suite 246; ITI 090.
3. ACGIH 18.
4. PPL 170.
5. Armour, MA, Brown, LM, and Plotinus, GL, J. Chem. Education, 62, A93, 1985; Armour, MA, J.
Chem. Education, 65, A64, 1988.
Hazardous laboratory chemicals disposal of lead 102
BROM Br2
Emit very POISONOUS RPA, to cause serious
BURNS
Physical Properties
Dark reddish brown liquid with a choking kipyatyaschiysya aroma; base point, 59.47 ° C.1
Chemical Properties
Slightly soluble {} soluble in water, freely soluble {} soluble in alcohol, ether, chloroform, carbon
tetrachloride, carbon disulfide, and the concentrated intensive} {hydrochloric acid 1
Hazardous Reactions
Acetone. Excess bromine causes sudden severe reaction 2
Acrylonitrile. Strong polymerization may result in three
Ammonia. Explosive red oil {butter} was formed upon cooling to -95 ° C after the interaction in the room {place}
Temperature 4
Diethyl ether.
